Cryogenic Liquid Safety

1. General precautions for all use of cryogenic liquids (continued)

  • Liquid nitrogen will condense oxygen from the air.  This is most alarmingly demonstrated if a person leaves his/her vacuum pump's coldfinger in a Dewar of liquid nitrogen overnight.  In the morning the coldfinger will contain LIQUID OXYGEN up to the level of the nitrogen in the Dewar.  Liquid oxygen is a significantly more hazardous cryogen because if it's properties as a powerful oxidant.
  • Guard against pressure build-up by using a pressure relief vessel or a venting lid.
  • Remove metal jewelry/watches on hand and wrists.
  • Glass Dewars must be taped solidly around the outside.  The plastic mesh with which some small thermoses are sold protects the Dewar itself to some extent, but does not protect very well against injury from glass shards resulting from implosion.
  • Use only vessels designed for extreme cold.  Not all Dewars are rated for liquid cryogens.  Be especially careful that any equipment used for use with liquid oxygen is rated for oxygen use, and is clean.  Always follow manufacturers' guidelines for use of cryogen vessels of any size.
  • Do not carry liquid cryogens in a passenger elevator.
  • Never work alone with hazards, always have at minimum two people moving a large Dewar in hallways, elevators, and outside of buildings.
  • Cryotubes containing samples stored under liquid nitrogen may explode without warning.  Tube explosions are thought to be caused by liquid nitrogen entering the tube through minute cracks and then expanding rapidly as the tube thaws.  Serious accidents have occurred around the country due to tube failures.  A researcher in California lost an eye; numerous others have suffered plastic shards embedded in their hands and faces.