Multiple Bragg Scattering and the Phase Problem. Applications to Quasicrystals and to Resonant Scattering
Friday December 02, 2005
Roberto Colella
Purdue University
Multiple Bragg Scattering, a situation in which two or more
Bragg reflections are excited at the same time, is a source
of phase information. Applications to quasicrystals will be
presented. The general problem of centrosymmetry, or lack of it,
will be discussed, along with experimental results.
Resonant scattering is a new technique used to get information
about "orbital ordering". The crystal potential gives rise to
preferred orientations of aspherical degenerate orbitals,
responsible for chemical bonding. This is commonly referred to
as "orbital ordering". One of the effects of orbital ordering
is to excite forbidden reflections when the energy of the x-rays
corresponds to an absorption edge. The phases of these forbidden
reflections may be very useful for a complete and accurate
description of orbital ordering. Applications will be shown for
Ge and LaMnO3. In the latter case, a recent 3-beam experiment
has resolved an ambiguity concerning the spatial distribution
of the Mn d-electrons.