Kansas State University
Probing Electron Transfer Times in Photosynthetic Reaction Centers by Hole-Burning Spectroscopy
Ryszard Jankowiak
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Tuesday March 20, 2012
1:30pm
PHYS 242
Coffee and doughnuts served at 1:15pm.
http://www.ksu.edu/chem/people/faculty/jankowiak.html
A brief discussion of transient hole-burned (HB) spectra (and information they provide) obtained for isolated reaction centers (RCs) from wild-type (WT) Rhodobacter sphaeroides, RCs containing zinc-bacteriochlorophylls (Zn-BChls) and RCs of Photosystem II (PSII) from spinach and Chlamydomonas reinhardtii, is presented. Regarding bacterial RCs, the shape of the density of states and the strength of electron-phonon coupling are re-examined. I focus, however, on heterogeneity of isolated RCs from spinach and in particular Chlamydomonas reinhardtii, site-energies of active (electron acceptor) and inactive pheophytins, the nature of the primary electron donor(s), and the possibility of multiple charge-separation (CS) pathways in isolated PSII RC.